It sounds like it's established and proven practice to remove the second catalysts, but I'm still at a loss to understand how it's possible.
Most cars have a single catalytic converter (per bank) but the RS6 and a few other "ordinary" cars with particularly powerful engines have two in series, but it's not for flow - they do two different jobs. If you do a google picture search for "reduction catalytic converter" or "oxidation catalytic converter" you'll find pictures like this:
https://gaukmotors.co.uk/post/catalytic-converter
Modern cars have 3-way catalysts, meaning that they convert three pollutants - NOx, HC & CO. NOx are reduced to N2 & O2 in the reduction catalyst, and HC & CO are oxidized to H20 & CO2 in the oxidation catalyst. Also see SSP 941003 page 20. Now here's the point - there are always two catalysts, and the reduction catalyst always comes first.
Therefore in the RS6 the small cat after the turbo is the reduction cat, and the large cat after the gearbox is the oxidation cat. And it's the oxidation cat that removes the HC & CO that the MoT tests for. The MoT doesn't test for NOx.
So how is it possible to pass the MoT without the oxidation catalyst? Well I'm scratching my head there. I can only guess that the reduction catalyst also does some oxidation as well, though perhaps not as efficiently as the oxidation cat.
Nick