Roy, that sounds like it's going to be a brilliant car. Can't wait to hear how you get on.
Mart, after market manufacturers sell 405 and 410mm front discs for the RS6, but I've never seen anyone offer 420m steel discs. It could be that the caliper won't "stretch" that far. Calipers are compatible with a modest range of disc diameters, but there are limits, and if you go too far the pads won't sit on the discs properly. 410mm is probably as far as you can go with the stock calipers. Once you have to upgrade the calipers, the upgrade is less cost effective.
The 420mm ceramic brakes have different calipers, and I think using them with steel discs would be difficult and expensive if not impossible (pad availability etc).
If you have larger wheels, there's a few companies that offer 430mm steel brake upgrades:
https://ceika-store.com/products/cbk77? ... udi~md_rs6
https://www.pbbrakes.com/audi-rs6-c6-08 ... e-kit.html
You're right about piston area and brake bias etc, though you don't take into account the increased leverage of the larger front discs, and it could be that 68% front bias isn't enough.
Nick