VCDS can do this looking at the label file for the engine 1 ECU and engine 2 ECU attached, but I've not tried this personally
It comes under blocks 060 onwards extract below, taken from 07L-910-552-BUH1.lbl
060,0,Electronic Throttle (Throttle Body Alignment)
060,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %
060,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %
060,3,Throttle Valve,Steps Counter,Range: 0...8\nSpecification: 8
060,4,Throttle Body,Alignment Status,Range: ADP RUN/ADP. O.K./ADP ERROR\nSpecification: ADP. O.K.
B060,0,Throttle Body Alignment
B060,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %
B060,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %
B060,3,Throttle Adaptation,Steps Counter,Range: 0...8\nSpecification: 8
B060,4,Throttle Body,Alignment Status,Range: ADP RUN/ADP OK/ADP ERROR\nSpecification: ADP OK
B060,11,Prerequisites: Ignition ON & Engine OFF
B060,12,The Throttle Body Alignment is completed when Field 4 shows "ADP OK".
061,0,Electronic Throttle
061,1,Engine Speed,(G28),Range: 0...6700 RPM\nSpecification (Idle): ~650 RPM
061,2,Battery Voltage,(Terminal 30),Specification: 11.0...15.0 V
061,3,Throttle Valve Angle,,Range: 0.0...100.0 %
061,4,Operating,Condition,x0xxx? = A/C Compressor\nx0xx?x = Gear engaged\nx0x?xx = A/C Readiness\nx0?xxx = Rear Window Heater\n?0xxxx = Front Window Heater
062,0,Electronic Throttle (Sensor Values)
062,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %
062,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %
062,3,Accel. Pedal Pos.,Sensor 1 (G79),Range: 0.0...100.0 %\nSpecification: 12.0...97.0 %
062,4,Accel. Pedal Pos.,Sensor 2 (G185),Range: 0.0...100.0 %\nSpecification: 4.0...49.0 %
063,0,Electronic Throttle (Kick-Down Alignment)
063,1,Accel. Pedal Pos.,Sensor 1 (G79),Range: 0.0...100.0 %\nSpecification: 12.0...97.0 %\nSpecification (Kick-Down): 79.0...94.0 %
063,2,Kick-Down,Alignment Value,Range: 0.0...100.0 %\nSpecification: 79.0...94.0 %
063,3,Kick-Down,Switch,Range: Kick Down
063,4,Kick-Down,Alignment Status,Range: ADP RUN/ADP OK/ADP ERROR\nSpecification: ADP OK
B063,0,Kick-Down Alignment (Automatic Transmission only)
B063,1,Throttle Position,Sensor (G79),Range: 0.0...100.0 %\nSpecification: 12.0...97.0 %\nSpecification (Kick-Down): 79.0...94.0 %
B063,2,Kick-Down,Alignment Value,Range: 0.0...100.0 %\nSpecification: 79.0...94.0 %
B063,3,Kick-Down,Switch,Range: Kick Down
B063,4,Kick-Down,Alignment Status,Range: ADP RUN/ADP OK/ADP ERROR\nSpecification: ADP OK
B063,11,Prerequisites: Ignition ON & Engine OFF
B063,12,Press the Accelerator Pedal down to the floor.
B063,13,Wait until Field 4 shows "ADP OK".
064,0,Electronic Throttle (Sensor Adaption Values)
064,1,Lower Adaptation,Sensor 1 (G187),Specification: 0.4...0.6 V
064,2,Lower Adaptation,Sensor 2 (G188),Specification: 4.0...5.0 V
064,3,Emergency Air Gap,Sensor 1 (G187),Specification: 0.5...1.0 V
064,4,Emergency Air Gap,Sensor 2 (G188),Specification: 4.0...5.0 V
It comes under blocks 062 onwards extract below, taken from 07L-910-552-BUH2.lbl
060,0,Electronic Throttle (Throttle Body Alignment)
060,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %\nSpecification (Idle): XX.0...XX.0 %
060,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %\nSpecification (Idle): XX.0...XX.0 %
060,3,Throttle Valve,Steps Counter,Range: 0...8\nSpecification: 8
060,4,Throttle Body,Alignment Status,Range: ADP RUN/ADP. O.K./ADP ERROR\nSpecification: ADP. O.K.
B060,0,Throttle Body Alignment
B060,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %\nSpecification (Idle): XX.0...XX.0 %
B060,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %\nSpecification (Idle): XX.0...XX.0 %
B060,3,Throttle Adaptation,Steps Counter,Range: 0...8\nSpecification: 8
B060,4,Throttle Body,Alignment Status,Range: ADP RUN/ADP OK/ADP ERROR\nSpecification: ADP OK
B060,11,Prerequisites: Ignition ON & Engine OFF
B060,12,The Throttle Body Alignment is completed when Field 4 shows "ADP OK".
061,0,Electronic Throttle
061,1,Engine Speed,(G28),Range: 0...6700 RPM\nSpecification (Idle): ~650 RPM
061,2,Battery Voltage,(Terminal 30),Specification: 11.0...15.0 V
061,3,Throttle Valve Angle,,Range: 0.0...100.0 %
061,4,Operating,Condition,x0xxx? = A/C Compressor\nx0xx?x = Gear engaged\nx0x?xx = A/C Readiness\nx0?xxx = Rear Window Heater\n?0xxxx = Front Window Heater
062,0,Electronic Throttle (Sensor Values)
062,1,Throttle Valve,Sensor 1 (G187),Range: 0.0...100.0 %\nSpecification: 3.0...93.0 %
062,2,Throttle Valve,Sensor 2 (G188),Range: 0.0...100.0 %\nSpecification: 97.0...3.0 %
062,3,Accel. Pedal Pos.,Sensor 1 (G79),Range: 0.0...100.0 %\nSpecification: 12.0...97.0 %
062,4,Accel. Pedal Pos.,Sensor 2 (G185),Range: 0.0...100.0 %\nSpecification: 4.0...49.0 %
064,0,Electronic Throttle (Sensor Adaption Values)
064,1,Lower Adaptation,Sensor 1 (G187),Specification: 0.4...0.6 V
064,2,Lower Adaptation,Sensor 2 (G188),Specification: 4.0...5.0 V
064,3,Emergency Air Gap,Sensor 1 (G187),Specification: 0.5...1.0 V
064,4,Emergency Air Gap,Sensor 2 (G188),Specification: 4.0...5.0 V
Always worth exploring those label files